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The meaning of this result is that the enthalpy of 1 mol of CO plus 1 mol of H 2 0 is greater than the enthalpy of 1 mol of C 0 2 plus 1 mol of Hz by 41 166 J when each product and reactant is taken as the pure gas at 29815 K (25 C) in the ideal-gas state at 1 bar In this example the standard heat of formation of H 2 0 is available for its hypothetical standard state as a gas at 29815 K (25 C) One might expect the value of the heat of formation of water to be listed for its actual state as a liquid at 1 bar and 29815 K (25 C) As a matter of fact, values for both states are given in Table C4 because they are both frequently used This is true for many compounds that normally exist as liquids at 29815 K (25 C) and the standard-state pressure Cases do arise, however, in which a value is given only for the standard

Including a CType overload that generates an Integer allowed me to convert a Bumblebee using the CInt operator. I could also have changed the last line to use the true CType operator.

state as a liquid or as an ideal gas when what is needed is the other value Suppose that this were the case for the preceding example and that only the standard heat of formation of liquid H20is known We must now include an equation for the physical change that transforms water from its standard state as a liquid into its standard state as a gas The enthalpy change for this physical process is the difference between the heats of formation of water in its two standard states:

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This last text trick is so simple you re going to say it s hardly a trick at all, but I m including it to show you how easy it is to come up with cool effects with very little effort The effect: text filled with a picture, as we ve already done, but this time the underlying picture is the same as the text How can you see the text at all, you wonder, if it s filled with the same image as the background The text is bordered on two sides, at least by a dark drop shadow Check out this:

This is approximately the latent heat of vaporization of water at 29815 K (25 C)The sequence of steps is now:

MsgBox("The swarm contains " & _ CType(swarmGroup, Integer) & " bees.")

co2(g> -+ c(s) + 02(g)

H2(g) + $2(g)

Here s how to do it: 1 Change the background color to white using the color palette 2 Click the Text button in the tool palette and click in the image to specify where the text will be pasted 3 In the Text Entry dialog box, make sure the Stroke and Fill styles are set to solid color, and choose Selection in the Create As section of the dialog box

As mentioned earlier, you must always make Operator methods Public Shared. And because the overloaded operators need some sort of intimate connection to their containing class, at least one of the operands or the return value must match the type of the containing class. (In some overloads, Visual Basic requires that it be one of the operands that match.) Either of the two following overloads will work just fine, since Bumblebee is used for one of the operands:

H20(1)

Only a few formation reactions can actually be carried out, and therefore data for these reactions must usually be determined indirectly One kind of reaction that readily lends itself to experiment is the combustion reaction, and many standard heats of formation come from standard

4 Enter the text and specify a font and size 5 Click OK to paste the text into the image 6 You should see a selection shaped like the text Just grab the text and drag it a short distance In place of the text you should see black lettering that will serve as your drop shadow Don t move the text too far, or the image text will get lost in the surrounding image

heats of combustion, measured calorimetrically A combustion reaction is defined as a reaction between an element or compound and oxygen to form specified combustion products For organic compounds made up of carbon, hydrogen, and oxygen only, the products are carbon dioxide and water, but the state of the water may be either vapor or liquid Data are always based on 1 mol o the substance burned f A reaction such as the formation of n-butane:

Public Shared Operator <=(ByVal operand1 As Bumblebee, _ ByVal operand2 As Integer) As Boolean ' ----- Compare a bumblebee to a value. End Operator

cannot be carried out in practice However, this equation results from combination of the following combustion reactions:

4C(s) + 5H2(g)

Public Shared Operator <=(ByVal operand1 As Date, _ ByVal operand2 As Bumblebee) As Boolean ' ----- Compare a date to a bumblebee. End Operator

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